Download PDF by L. A. Tavadyan, G. A. Martoyan: Analysis of Kinetic Models of Chemical Reaction Systems:

By L. A. Tavadyan, G. A. Martoyan

ISBN-10: 1631178652

ISBN-13: 9781631178658

English model of: Analiz kineticheskikh modelei khimicheskikh reak'tsionnykh sistem.

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Extra resources for Analysis of Kinetic Models of Chemical Reaction Systems: Value Approach

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Similarly the value of the reaction system species is defined as the response of a selected target parameter at time t, to a small perturbation of the rate-of-production of species i at time t0 32 L. A. Tavadyan and G. A. 4) where fi(t) = dci/dt is the rate-of -production of the i-th reaction species. Value quantities of the species and individual steps are strictly interconnected through chemical equations of individual steps in the following form: a jl Ll   a jp Pp l p where a jp , a jl are the stoichiometric coefficients for the j-th step, and p and l are the indices pertinent to the products and the initial compounds of the j-th step, respectively, L and P note the initial compounds and reaction products.

5) it is necessary that the life-time of each intermediate species is considerably smaller than the reaction-time. A detailed description of the pathway theory‟s basics is given in [14-21]. Here we describe briefly only some results. Let us get to know the fundamentals of this theory. The reaction pathway specifies one of the paths of a steady-state chemical transformation and represents a set of individual steps with corresponding stoichiometric numbers, the sum of which (the resulting chemical equation) does not contain active intermediates.

MATHEMATICAL METHODS FOR IDENTIFICATION OF KINETIC SIGNIFICANCE OF INDIVIDUAL STEPS IN CHEMICAL REACTION SYSTEMS In this section the more formalized methods on determining the role of individual steps in complex chemical reactions are briefly described. 1. Analytical Description of Kinetic Regularities of Chemical Reactions Analytical description of the chemical reaction progress with time, within the framework of a specific model, enables mostly to identify the kinetic significance of the individual steps, as a dependence of the rates or concentrations of the reaction species on the rate constants of the contributing steps and the measured values.

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Analysis of Kinetic Models of Chemical Reaction Systems: Value Approach by L. A. Tavadyan, G. A. Martoyan


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